[(Z)-1-({3-[(3-Aminopropyl)(2-nitrobenzyl)amino]propyl}iminomethyl)naphthalen-2-olato]copper(II) perchlorate
نویسندگان
چکیده
In the title compound, [Cu(C(24)H(27)N(4)O(3))]ClO(4), the Cu(II) atom has a distorted square-planar coordination geometry and is surrounded by an N(3)O donor set composed of a secondary amine N, a primary amine H, an imino N and a naphthalen-2-olate O atom. An intra-molecular N-H⋯O hydrogen bond occurs. In the crystal, mol-ecules are held together by inter-molecular N-H⋯O hydrogen bonds, leading to the formation of a three-dimensional network.
منابع مشابه
[2-({3-[(3-Aminopropyl)amino]propyl}iminomethyl)phenolato-κ4 O,N,N′′,N′′′]bromidocopper(II)
In the title compound, [Cu(C(13)H(20)N(3)O)Br], the Cu(II) atom is coordinated by three N atoms and one O atom from the deprotonated ligand derived from the Schiff base condensation of 3,3-imino-bis-(propyl-amine) and salicyl-aldehyde. The three N and the O atoms occupy equatorial positions, while the Br atom occupies an axial position. The amine H atoms form inter-molecular hydrogen bonds with...
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متن کاملBis{1-[(E)-(2-chlorophenyl)diazenyl]naphthalen-2-olato}copper(II)
The Cu(II) atom in the title compound, [Cu(C16H10ClN2O)2], is located on an inversion center and is tetra-coordinated by two N and two O atoms from two bidentate 1-[(E)-(2-chloro-phen-yl)diazen-yl]naphthalen-2-olate ligands, forming a square-planar complex. In the crystal, mol-ecules are linked via weak C-H⋯O and C-H⋯Cl hydrogen bonds, forming chains propagating along [010]. There are also π-π ...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011